[meteorite-list] Ringwoodite and water found in a diamond

[MEM]

First time ringwoodite has been identified in terrestrial rock.  (I see no mention that a carbonado has been ruled out/excluded so I am relying on the report as -is)
Elton



<http://www.nature.com/news/tiny-diamond-impurity-reveals-water-riches-of-deep-earth-1.14862>

A microscopic crystal of a mineral never before seen in a terrestrial rock holds clues to the presence of vast quantities of water deep in 
Earth’s mantle, scientists report in a paper published today in Nature. The discovery came from a diamond weighing less than one-tenth of a 
gram, found in Brazil. Further studies of the sample could help to 
answer the long-standing question of the origin of the planet's water.

Most diamonds form at depths of about 150 
to 200 kilometres, but 'ultradeep' diamonds come from a region of the 
mantle known as the transition zone, 410 to 660 kilometres below the 
surface, says Graham Pearson, a mantle geochemist at the University of 
Alberta in Edmonton and the lead author of the study.
Impurities in ultradeep diamonds can be used as probes to study the regions in 
which the stones formed — and in particular to understand what minerals 
are present at those depths. Certain minerals have crystal structures 
that can form only at high pressures or temperatures, or both, and many 
rearrange themselves into different structures when the pressure is 
taken off or the temperature goes down. Thus, when the churning of the 
mantle brings rock towards the surface, some of the minerals that formed at great depths can no longer be found. But if the minerals are trapped inside diamonds, they stay compressed in their original forms. “These 
high-pressure diamonds give you a window into the deep Earth,” says 
Pearson.

He and his team studied one such diamond, 
which weighed 0.09 grams and came from the Juína district in Brazil. As 
they  examined impurities in it using a light-scattering method known as Raman spectroscopy, they came across something unusual: a grain 40 
micrometres across that turned out to be ringwoodite — a high-pressure 
form of olivine, a mineral that makes up much of the upper mantle. 
Ringwoodite had previously been found only in meteorites or synthesized 
in the lab.
Rock star
Mineralogical theory and seismic findings had long suggested that ringwoodite is a 
major component of the transition zone, and the finding backs that up. 
“It confirms that our ideas of how the mantle is constructed are 
correct,” says Hans Keppler, a geophysicist at the University of 
Bayreuth in Germany, who wrote about the find in an accompanying News 
& Views2.
Unlike better-studied forms of olivine, ringwoodite can hold a substantial 
amount of water. The sample therefore had the potential to help resolve a long-standing controversy over just how much water the transition zone 
contains. Using infrared spectroscopy, Pearson’s team found that its 
tiny fleck of ringwoodite contained about 1% water by weight. “That may 
not sound like much,” Pearson says, “but when you realize how much 
ringwoodite there is, the transition zone could hold as much water as 
all the Earth’s oceans put together.”
But the 
water content of a single crystal is not necessarily representative of 
the entire zone, says Norm Sleep, a geophysicist at Stanford University 
in California. Diamonds are produced by an unusual type of volcanism 
that is normally associated with water-rich rock, he says. He compares 
the situation to that of someone panning for gold and finding a large 
nugget: “It would be unwise to assume that all the gravel in the stream 
is gold nuggets.”


Pearson agrees. Remote-sensing studies of the mantle have produced conflicting 
results, suggesting that the water content of the transition zone may be “spotty”, he says. “Our sample appears to come from one of the wet 
spots.”
Where it all began
There are two theories as to where the mantle's water came from. One is that 
it was ocean water that was carried deep underground when sea-floor 
rocks were subducted by plate tectonics. The other is that deeper layers of the Earth still contain water that was part of the materials that 
formed the Earth.
If the water has been there 
since Earth formed, its ratio of deuterium to normal hydrogen could be 
different from that found in sea water today—and closer to the 
composition of the Earth’s primordial water.  If so, that ratio could 
provide clues as to whether the water came from asteroids or from 
comets, says Humberto Campins, an asteroid researcher at the University 
of Central Florida in Orlando.
Pearson sees a 
value to checking the isotope ratio, but so far his group has been 
unwilling to do such destructive tests on the only known piece of mantle ringwoodite. “We have to think really carefully on what we do next on 
this sample because it’s very small: 40 micrometres,” he says. “That 
means you can only think of doing one or two additional analyses.”